ntvНаучно-технический вестник информационных технологий, механики и оптикиScientific and Technical Journal of Information Technologies, Mechanics and Optics2226-14942500-0373Университет ИТМО10.17586/2226-1494-2023-23-6-1136-1142ntv-21Research ArticleНОВЫЕ МАТЕРИАЛЫ И НАНОТЕХНОЛОГИИMATERIAL SCIENCE AND NANOTECHNOLOGIESРамановская спектроскопия нанокомпозитов ZnO/ZnS и ZnO/ZnSe, полученных методом сольвотермического микроволнового синтезаRaman spectroscopy of nanocomposites ZnO/ZnS and ZnO/ZnSe obtained by solvothermal-microwave synthesis methodhttps://orcid.org/0000-0003-0222-6014РатиИ.RatiY.

Рати Иоланда — магистр

Бандунг, 40132

sc 57221219077

Yolanda Rati — Master Student

Bandung, 40132

sc 57221219077

yolandarati@gmail.comhttps://orcid.org/0000-0002-5435-2568РиниА. С.RiniA. S.

Рини Ари Сулистьо — доктор наук, преподаватель

Пеканбару, 28293

sc 36059915000

Ari Sulistyo Rini — D.Sc., Senior Lecturer

Pekanbaru, 28293

sc 36059915000

ari.sulistyo@lecturer.unri.ac.idhttps://orcid.org/0000-0001-8299-4827АкраджасА. У.AkrajasA. U.

Акраджас Али Умар — доктор наук, преподаватель

Селангор, 43600

sc 9332520900

Ali Umar Akrajas — D.Sc., Senior Lecturer

Selangor, 43600

akrajas@ukm.edu.myhttps://orcid.org/0009-0007-1358-0496АгустинМ.AgustinM.

Агустин Миранти — студент

Пеканбару, 28293

sc 57221219077

 

Miranti Agustin — Student

Pekanbaru, 28293

sc 57221219077

mirantiagustin17@gmail.comБандунгский технологический институтИндонезияInstitut Teknologi BandungIndonesiaУниверситет РиауИндонезияUniversitas RiauIndonesiaНациональный университет МалайзииМалайзияUniversiti Kebangsaan MalaysiaMalaysia20231112202423611361142Copyright © Рати И., Рини А.С., Акраджас А.У., Агустин М., 20242024Рати И., Рини А.С., Акраджас А.У., Агустин М.Rati Y., Rini A.S., Akrajas A.U., Agustin M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://ntv.elpub.ru/jour/article/view/21

Представлены нанокомпозиты ZnO/ZnS и ZnO/ZnSe, синтезированные сольвотермо-микроволновым методом. Для объяснения режима фононных колебаний применен метод рамановской спектроскопии. Полученная высокая интенсивность рамановского рассеяния подтвердила высокочастотную фононную моду гексагонального вюрцита ZnO. Наличие интенсивного комбинационного рассеяния света кубических структур ZnS и ZnSe свидетельствует о существовании продольной оптической фононной моды. Обнаружены небольшие сдвиги во всех модах ZnO для ZnO/ZnS и ZnO/ZnSe, которые указывают на наличие напряжения и деформации в кристаллической решетке. Исследованы изменения размера частиц с помощью конфокальной рамановской микроскопии. Показано, что изменения структуры и размеров частиц материала улучшили его характеристики. Подтверждено, что нанокомпозитные гетероструктуры, полученные простым химическим методом, применимы для создания оптоэлектронных устройств.

We report the ZnO/ZnS and ZnO/ZnSe nanocomposites synthesized using the solvothermal-microwave method. Raman analysis was thoroughly studied to explain phonon vibration mode in this paper. The strong intensity confirms the highfrequency phonon mode of hexagonal wurtzite ZnO. Also, the presence of Raman intensity of the cubic ZnS and ZnSe structures indicates the longitudinal optical phonon mode. In addition, we find several slight shifts in all ZnO modes for ZnO/ZnS and ZnO/ZnSe which demonstrate stress and strain in the crystal lattice. We investigate the change in particle size from confocal Raman microscopy. Therefore, the modifications to the material structure and particle size have enhanced its characteristics. Accordingly, the nanocomposite heterostructures by the simple chemical method are attractive materials suitable for optoelectronic devices.

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The authors declare that there are no conflicts of interest present.