ntvНаучно-технический вестник информационных технологий, механики и оптикиScientific and Technical Journal of Information Technologies, Mechanics and Optics2226-14942500-0373Университет ИТМО10.17586/2226-1494-2024-24-6-936-942ntv-399Research ArticleНОВЫЕ МАТЕРИАЛЫ И НАНОТЕХНОЛОГИИMATERIAL SCIENCE AND NANOTECHNOLOGIESСпектрально-люминесцентные свойства серебряных кластеров Ag1-5 в ионообменном слое силикатного стеклаSpectral-luminescent properties of silver clusters Ag1-5 in the ion-exchange layer of silicate glasshttps://orcid.org/0009-0003-6052-7517ПесняковВ. В.PesnyakovV. V.

Песняков Владислав Викторович - инженер, 

Санкт-Петербург, 197101

Vladislav V. Pesnyakov - Engineer, 

Saint Petersburg, 197101

v.pesnyackoff@yandex.ruhttps://orcid.org/0000-0001-8480-2016МарасановД. В.MarasanovD. V.

Марасанов Дмитрий Вячеславович - кандидат физико-математических наук, ведущий инженер,

Санкт-Петербург, 197101

Dmitriy V. Marasanov - PhD (Physics & Mathematics), Leading Engineer,

Saint Petersburg, 197101

dmitriymarasanov@bk.ruhttps://orcid.org/0000-0002-0160-8443ЕвстропьевС. К.EvstropievS. K.

Евстропьев Сергей Константинович - доктор химических наук, ведущий научный сотрудник, Санкт-Петербург, 197101;

начальник отдела, Санкт-Петербург, 192171;

профессор, Санкт-Петербург, 190013

Sergey K. Evstropiev - D.Sc. (Chemistry), Leading Researcher, Saint Petersburg, 197101;

Head of Department, Saint Petersburg, 192171;

Professor, Saint Petersburg, 190013

evstropiev@bk.ruhttps://orcid.org/0000-0002-1341-067XНиконоровН. В.NikonorovN. V.

Никоноров Николай Валентинович - доктор физико-математических наук, профессор, профессор,

Санкт-Петербург, 197101

Nikolay V. Nikonorov - D.Sc. (Physics & Mathematics), Full Professor,

Saint Petersburg, 197101

nikonorov@oi.ifmo.ruУниверситет ИТМОРоссияITMO UniversityRussian FederationУниверситет ИТМО; Научно-производственное объединение Государственный оптический институт им. С.И. Вавилова; Санкт-Петербургский государственный технологический институт (технический университет)РоссияITMO University; JVC “RPA Vavilov State Optical Institute”; Saint Petersburg State Institute of TechnologyRussian Federation202428122024246936942Copyright © Песняков В.В., Марасанов Д.В., Евстропьев С.К., Никоноров Н.В., 20242024Песняков В.В., Марасанов Д.В., Евстропьев С.К., Никоноров Н.В.Pesnyakov V.V., Marasanov D.V., Evstropiev S.K., Nikonorov N.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://ntv.elpub.ru/jour/article/view/399Введение

Введение. В работе впервые показана селективность люминесценции молекулярных кластеров серебра в силикатном стекле, сформированных методом ионного обмена из солевого расплава, содержащего 0,1 % AgNO3/99,9 % NaNO3 мол.%.

Метод

Метод. В исследовании использованы коммерческие силикатные предметные стекла системы: SiO2-Na2O-K2O-CaO-MgO-Al2O3 с примесями Fe2O3-SO3. Молекулярные кластеры были получены методом низкотемпературного ионного обмена в расплаве 0,1 % AgNO3/99,9 % NaNO3 мол.% в течение 10 и 15 мин при температуре 320 °С.

Основные результаты

Основные результаты. Исследованы люминесцентные свойства серебряных молекулярных кластеров в ионообменном слое предметных стекол. На спектрах люминесценции обнаружены полосы кластеров серебра различного размера (Ag1–5). При этом кластеры Ag1–3 возбуждаются излучением с более короткими длинами волн, а кластеры Ag4–5 — только излучением дальнего ультрафиолетового диапазона и видимого диапазона с длиной волны до 500 нм. В процессе ионного обмена длительностью до 10 мин выявлено появление селективности люминесценции, которая возникает за счет присутствия в ионообменном слое малой концентрации кластеров различного размера Ag1–5.

Обсуждение

Обсуждение. Полученные результаты могут найти применение при разработке фоточувствительного элемента селективного детектора ультрафиолетового излучения.

This work demonstrates for the first time the selectivity of silver molecular clusters luminescence in silicate glass formed by the ion exchange method from a salt melt containing 0.1 mol.% silver nitrate (AgNO3) and 99.9 mol.% sodium nitrate (NaNO3). Commercial silicate microscope slides of the following system were used: SiO2-Na2O-K2O-CaO-MgO-Al2O3 with Fe2O3-SO3 impurities. Molecular clusters were obtained by low-temperature ion exchange in a melt of 0.1 % AgNO3/99.9 % NaNO3 mol.% for 10 and 15 min at 320°C. The luminescent properties of silver molecular clusters in the ion-exchange layer of microscope slides were studied. Bands of silver clusters of different sizes (Ag1-5) were found in the luminescence spectra. In this case, clusters Ag1-3 are excited by shorter wavelengths, and clusters Ag4-5 only by far ultraviolet and visible radiation up to 500 nm. In the process of ion exchange lasting up to 10 minutes, the appearance of luminescence selectivity was revealed, which occurs due to the presence of a low concentration of silver clusters of different sizes Ag1-5 in the ion-exchange layer. The obtained results can be used in the development of a photosensitive element for a selective ultraviolet radiation detector.

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The authors declare that there are no conflicts of interest present.