ntvНаучно-технический вестник информационных технологий, механики и оптикиScientific and Technical Journal of Information Technologies, Mechanics and Optics2226-14942500-0373Университет ИТМО10.17586/2226-1494-2026-26-4-695-704ntv-637Research ArticleОПТИЧЕСКИЕ СИСТЕМЫ И ТЕХНОЛОГИИOPTICAL ENGINEERINGВозможности применения методов колебательной спектроскопии для определения парниковых газов на карбоновом полигоне «Росянка» (Калининградская область)A feasibility study of vibrational spectroscopy methods for greenhouse gas detection at the “Rossyanka” Carbon Measurement Supersite (Kaliningrad Oblast, Russia)https://orcid.org/0000-0002-9766-1408ЗюбинА. Ю.ZyubinA. Y.

Зюбин Андрей Юрьевич — доктор физико-математических наук, старший научный сотрудник

sc 57193159520

Калининград, 236041

Andrey Y. Zyubin — D.Sc. (Physics & Mathematics), Senior Researcher

sc 57193159520

Kaliningrad, 236041

azubin@mail.ruhttps://orcid.org/0009-0001-1584-6741ОпаринЯ. С.OparinYa. S.

Опарин Ярослав Сергеевич —  студент

Калининград, 236041

Yaroslav S. Oparin — Student

Kaliningrad, 236041

yoparyn@mail.ruhttps://orcid.org/0009-0003-8799-0392КнязьковИ. Д.KnyazkovI. D.

Князьков Игорь Дмитриевич — студент

Калининград, 236041

Igor D. Knyazkov — Student

Kaliningrad, 236041

ikoroleva@kantiana.ruhttps://orcid.org/0000-0001-7612-4454КоролеваЮ. В.KorolevaYu. V.

Koролева Юлия Владимировна — кандидат географических наук, доцент

sc 57194705244

Калининград, 236041

Yulia V. Koroleva — PhD (Geography), Associate Professor, Associate Professor

sc 57194705244

Kaliningrad, 236041

ikoroleva@kantiana.ruhttps://orcid.org/0000-0002-0889-7276НапреенкоМ. Г.NapreenkoM. G.

Напреенко Максим Геннадьевич — кандидат биологических наук, ведущий научный сотрудник

sc 57192004687

Калининград, 236041

Maxim G. Napreenko — PhD (Biology), Leading Researcher

sc 57192004687

Kaliningrad, 236041

ikoroleva@kantiana.ruhttps://orcid.org/0000-0003-3083-0649БашироваЛ. Д.BashirovaL. D.

Баширова Лейла Джангировна — кандидат геолого-минералогических наук, директор НОЦ «Геоэкология и морское природопользование»

sc 55372913900

Калининград, 236041

Leyla D. Bashirova — PhD (Geology & Mineralogy), Director of the Scientific and Educational Center “Environmental Geology and Marine Nature Management”

sc 55372913900

Kaliningrad, 236041

bas_leila@mail.ruhttps://orcid.org/0000-0001-5026-7510СамусевИ. Г.SamusevI. G.

Самусев Илья Геннадьевич — кандидат физико-математических наук, директор НОЦ «Фундаментальная и прикладная фотоника. Нанофотоника»

sc 12779220200

Калининград, 236041

Ilya G. Samusev — PhD (Physics & Mathematics), Head of the Research and Educational Center “Fundamental and Applied Photonics. Nanophotonics”

sc 12779220200

Kaliningrad, 236041

isamusev@kantiana.ruБалтийский федеральный университет имени Иммануила КантаРоссияImmanuel Kant Baltic Federal UniversityRussian Federation202627082026264695704Copyright © Зюбин А.Ю., Опарин Я.С., Князьков И.Д., Королева Ю.В., Напреенко М.Г., Баширова Л.Д., Самусев И.Г., 20262026Зюбин А.Ю., Опарин Я.С., Князьков И.Д., Королева Ю.В., Напреенко М.Г., Баширова Л.Д., Самусев И.Г.Zyubin A.Y., Oparin Y.S., Knyazkov I.D., Koroleva Y.V., Napreenko M.G., Bashirova L.D., Samusev I.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://ntv.elpub.ru/jour/article/view/637

Введение. Представлены результаты применения методов колебательной спектроскопии для мониторинга парниковых газов на карбоновом полигоне «Росянка» (Калининградская область). Использование предложенных методов демонстрирует эффективность при полуколичественном обнаружении парниковых газов, в частности углекислого газа (CO2). Показан потенциал применения инфракрасной спектроскопии и спектроскопии комбинационного рассеяния света (КРС) для мониторинга CO2 в полевых условиях с разницей значений порядка 100 мг/л между рассчитанными и экспериментальными значениями концентраций в полевых образцах.  Метод. Применены методы инфракрасной спектроскопии и спектроскопии комбинационного рассеяния света с использованием спектрометра Virsa (компания «Renishaw», Великобритания) и Shimadzu IR-Prestige 21. Съемка производилась путем регистрации спектров газов, укупоренных в стеклянный флакон для лекарственных средств объемом 10 мл. Выполнялось сравнение полученных образцов спектров газовой смеси со спектрами эталонного образца с известной концентрацией, а также cо значением концентраций, полученных с использованием газового хроматографа. Основные результаты. Продемонстрирована принципиальная возможность применения методов инфракрасной спектроскопии и спектроскопии комбинационного рассеяния света для определения концентраций парниковых газов на карбоновых полигонах страны, в том числе, на карбоновом полигоне «Росянка», где при определении содержания CO2 в воздухе порог регистрации составил 300–500 мг/л. Обсуждение. Для образцов, отобранных на карбоновом полигоне «Росянка», применяемые методы колебательной спектроскопии позволили определить только концентрацию CO2. Концентрации метана не были определены из-за их низких значений в образцах (до 10 мг/л по данным газовой хроматографии). Ожидается, что дальнейшие исследования с применением методов усиления сигнала, например с использованием многоходовых кювет или резонаторноусиленная спектроскопия комбинационного рассеяния света, позволят решить эту проблему при регистрации низких значений концентрации парниковых газов. 

The paper presents the results of an investigation that employed vibrational spectroscopy as a monitoring technique for greenhouse gases at the “Rossyanka” Carbon Measurement Supersite, in Kaliningrad Oblast. The application of these methodologies is indicative of their efficacy in the quantitative detection of greenhouse gases, with a particular focus on carbon dioxide (CO2). The capacity of infrared (IR) and Raman spectroscopy (RS) for the monitoring of O2 in field conditions is illustrated, with a discrepancy of approximately 100 ppm observed between the calculated and experimental values of concentrations in field samples. Methods of IR and RS using a Virsa (Renishaw) and Shimadzu IRPrestige 21 spectrometer have been applied. The survey was carried out by recording the spectra of gases sealed in a glass vial for medicines with a volume of 10 ml. The obtained samples of the spectra of the gas mixture were compared with the spectra of a reference sample with a known concentration. The results demonstrate the feasibility of using IR and RS wile determine greenhouse gas concentrations at carbon supersites throughout the country, including the “Rossyanka” Carbon Measurement Supersite where CO2 concentrations can be determined with a registration threshold of 300500 ppm and the isolation of the main characteristic vibrational modes. For the samples obtained at the “Rossyanka” Carbon Measurement Supersite, the applied vibrational spectroscopy methods enabled the quantification of only the concentration of CO2. The presence of CH4 was not detected in the samples due to the low concentrations of the gas which were found to be as low as 10 ppm according to gas chromatography. It is expected that further studies using signal amplification methods, such as using multi-pass cuvettes, will solve this problem when registering low greenhouse gas concentrations. It is expected that further studies using signal amplification methods, such as using multi-pass cuvettes and RS, will solve this problem when registering low greenhouse gas concentrations. 

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The authors declare that there are no conflicts of interest present.