Low-temperature cell for IR Fourier spectrometric investigation of hydrocarbon substances
https://doi.org/10.17586/2226-1494-2023-23-4-696-702
Abstract
A specialized low-temperature measuring cell with a cryogenic capillary system for infrared spectral analysis of ethanol developed by the authors is presented. The use of the created low-temperature cell is possible for further studies of the low-temperature properties of both pure ethanol and mixtures with its contents, which is currently an urgent task, and the data obtained with its help can be used for ice research. Two methods of ethanol research at low temperature are presented in comparison. In the frst method proposed by the authors, a specially developed low-temperature measuring cell based on a diffuse refection prefx of the Fourier spectrometer FSM 2203 with a cryogenic capillary system is used. This system allows you to achieve the required low-temperature regime at normal atmospheric pressure. The results of the experiment are compared with the traditional method of gas-phase condensation of the test sample under low temperature conditions at the pressure P = 1.0·10–5 Torr. Infrared spectra of low molecular weight amorphous and crystalline ethanol were obtained at a temperature of 150 K at normal atmospheric pressure and in vacuum. Comparison of experimental results confrmed the operability of the new installation. In the experiments, peaks were observed in the absorption bands from 2850 to 3000 cm–1 and from 2950 to 3100 cm–1, corresponding to the valence CH vibrations of ethanol as well as in the absorption bands from 3150 to 3400 cm–1 and from 3300 to 3500 cm–1, which corresponds to the valence vibrations of OH. The results of the study showed the prospects of the proposed method and can be useful by researchers in the feld of low-temperature spectroscopy at normal pressure.
Supporting agencies: This research was carried out under grant AP15473758 with the fnancial support of the Ministry of Education and Science of the Republic of Kazakhstan.
About the Authors
A. A. Kenbay
Al-Farabi Kazakh National University
Kazakhstan
Kazakhstan
Alisher A. Kenbay — Doctoral Student
Almaty, 050040
O. Yu. Golikov
Al-Farabi Kazakh National University
Kazakhstan
Kazakhstan
Oleg Yu. Golikov — Doctoral Student, Junior Researcher
sc 57843805800
Almaty, 050040
A. U. Aldiyarov
Al-Farabi Kazakh National University
Kazakhstan
Kazakhstan
Abdurakhman U. Aldiyarov — PhD (Physics & Mathematics), Associatу Professor, Acting Professor
sc 57843805800
Almaty, 050040
D. E. Yerezhep
Al-Farabi Kazakh National University; Institute of Physics and Technology, Satbayev University; Satbayev University
Kazakhstan
Kazakhstan
Darkhan E. Yerezhep — PhD, Senior Lecturer; Leading Reseacher; Associate Professor
sc 57194012596
Almaty, 050040
Almaty, 050032
Almaty, 050013
References
1. Vinatier S., Schmitt B., Bézard B., Rannou P., Dauphin C., de Kok R., Jennings D.E., Flasar F.M. Study of Titan’s fall southern stratospheric polar cloud composition with Cassini/CIRS: Detection of benzene ice. Icarus, 2018, vol. 310, pp. 89–104. https://doi.org/10.1016/j.icarus.2017.12.040
2. Cernicharo J., Heras A.M., Tielens A.G.G.M., Pardo J.R., Herpin F., Guélin M., Waters L.B.F.M. Infrared space observatory’s discovery of C4H2, C6H2, and benzene in CRL 618. Astrophysical Journal, 2001, vol. 546, no. 2, pp. L123–L126. https://doi.org/10.1086/318871
3. Loerting T., Fuentes-Landete V., Handle P.H., Seidl M., AmannWinkel K., Gainaru C., Böhmer R. The glass transition in highdensity amorphous ice. Journal of Non-Crystalline Solids, 2015, vol. 407, pp. 423–430. https://doi.org/10.1016/j.jnoncrysol.2014.09.003
4. Yarnall Y.Y., Hudson R.L. Crystalline ices — Densities and comparisons for planetary and interstellar applications. Icarus, 2022, vol. 373, pp. 114799. https://doi.org/10.1016/j.icarus.2021.114799
5. Yarnall Y.Y., Hudson R.L. Infrared intensities of methyl acetate, an interstellar compound — comparisons of three organic esters. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022, vol. 283, pp. 121738. https://doi.org/10.1016/j.saa.2022.121738
6. Gibb E.L., Whittet D.C.B., Boogert A.C.A., Tielens A.G.G.M. Interstellar ice: The Infrared Space Observatory legacy. Astrophysical Journal Supplement Series, 2004, vol. 151, no. 1, pp. 35–73. https://doi.org/10.1086/381182
7. Hudson R.L., Mullikin E.F. Infrared band strengths for amorphous and crystalline methyl propionate, a candidate interstellar molecule. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, vol. 207, pp. 216–221. https://doi.org/10.1016/j.saa.2018.09.032
8. Allamandola L.J., Sandford S.A., Tielens A.G.G.M., Herbst T.M. Infrared spectroscopy of dense clouds in the C-H stretch region - Methanol and “diamonds”. Astrophysical Journal, 1992, vol. 399, pp. 134. https://doi.org/10.1086/171909
9. Shelar M.N., Matsagar V.K., Patil V.S., Barahate S.D. Net energy analysis of sugarcane based ethanol production. Cleaner Energy Systems, 2023, vol. 4, pp. 100059. https://doi.org/10.1016/j.cles.2023.100059
10. Li X., Dong Y., Chang L., Chen L., Wang G., Zhuang Y., Yan X. Dynamic hybrid modeling of fuel ethanol fermentation process by integrating biomass concentration XGBoost model and kinetic parameter artifcial neural network model into mechanism model. Renewable Energy, 2023, vol. 205, pp. 574–582. https://doi.org/10.1016/j.renene.2023.01.113
11. Kumar S., Cho J.H., Park J., Moon I. Advances in diesel–alcohol blends and their effects on the performance and emissions of diesel engines. Renewable and Sustainable Energy Reviews, 2013, vol. 22, pp. 46–72. https://doi.org/10.1016/j.rser.2013.01.017
12. Wei L., Cheung C.S., Ning Z. Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine. Energy, 2018, vol. 155, pp. 957–970. https://doi.org/10.1016/j.energy.2018.05.049
13. Miao W.G., Tang C., Ye Y., Quinn R.J., Feng Y. Traditional Chinese medicine extraction method by ethanol delivers drug-like molecules. Chinese Journal of Natural Medicines, 2019, vol. 17, no. 9, pp. 713– 720. https://doi.org/10.1016/s1875-5364(19)30086-x
14. Day S.M., Gironda S.C., Clarke C.W., Snipes J.A., Nicol N.I., Kamran H., Vaughan W., Weiner J.L., Macauley S.L. Ethanol exposure alters Alzheimer’s-related pathology, behavior, and metabolism in APP/PS1 mice. Neurobiology of Disease, 2023, vol. 177, pp. 105967. https://doi.org/10.1016/j.nbd.2022.105967
15. Zhang L., Shen Q., Pang C.H., Chao W., Tong S., Kow K.W., Lester E., Wu T., Shang L., Song X., Sun N., Wei W. Life cycle assessment of bio-fermentation ethanol production and its infuence in China’s steeling industry. Journal of Cleaner Production, 2023, vol. 397, pp. 136492. https://doi.org/10.1016/j.jclepro.2023.136492
16. Lui M.Y., Masters A.F., Maschmeyer T., Yuen A.K.L. Molybdenum carbide, supercritical ethanol and base: Keys for unlocking renewable BTEX from lignin. Applied Catalysis B: Environmental, 2023, vol. 325, pp. 122351. https://doi.org/10.1016/j.apcatb.2022.122351
17. Hudson R.L. An IR investigation of solid amorphous ethanol – Spectra, properties, and phase changes. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2017, vol. 187, pp. 82–86. https://doi.org/10.1016/j.saa.2017.06.027
18. Materese C.K., Gerakines P.A., Hudson R.L. Laboratory studies of astronomical ices: Reaction chemistry and spectroscopy. Accounts of Chemical Research, 2021, vol. 54, no. 2, pp. 280–290. https://doi.org/10.1021/acs.accounts.0c00637
19. Hudgins D.M., Sandford S.A., Allamandola L.J., Tielens A.G.G.M. Mid- and far-infrared spectroscopy of ices - Optical constants and integrated absorbances. Astrophysical Journal Supplement Series, 1993, vol. 86, pp. 713. https://doi.org/10.1086/191796
20. Drobyshev A., Aldiyarov A., Sokolov D., Shinbaeva A., Nurmukan A. IR Spectrometry studies of methanol cryovacuum condensates. Low Temperature Physics, 2019, vol. 45, no. 4, pp. 441–451. https://doi.org/10.1063/1.5093525
21. Drobyshev A., Aldiyarov A., Sokolov D., Shinbayeva A., Tokmoldin N. Refractive indices vs deposition temperature of thin flms of ethanol, methane and nitrous oxide in the vicinity of their phase transition temperatures. Low Temperature Physics, 2017, vol. 43, no. 10, pp. 1214–1216. https://doi.org/10.1063/1.5008415
22. Boogert A.C.A., Gerakines P.A., Whittet D.C.B. Observations of the icy universe. Annual Review of Astronomy and Astrophysics, 2015, vol. 53, no. 1, pp. 541–581. https://doi.org/10.1146/annurev-astro-082214-122348
23. Hudson R.L. Infrared spectra of benzene ices: Reexamination and comparison of two recent papers and the literature. Icarus, 2022, vol. 384, pp. 115091. https://doi.org/10.1016/j.icarus.2022.115091
24. Hudson R.L., Gerakines P.A., Yarnall Y.Y. Ammonia ices revisited: New IR intensities and optical constants for solid NH3. Astrophysical Journal, 2022, vol. 925, no. 2, pp. 156. https://doi.org/10.3847/1538-4357/ac3e74
25. The Science of Solar System Ices. Ed. by M.S. Gudipati, J. CastilloRogez. New York, NY, Springer New York, 2013. Astrophysics and Space Science Library; V. 356. https://doi.org/10.1007/978-1-4614-3076-6
26. Sokolov D.Y., Yerezhep D., Vorobyova O., Golikov O., Aldiyarov A.U. Infrared analysis and effect of nitrogen and nitrous oxide on the glass transition of methanol cryoflms. ACS Omega, 2022, vol. 7, no. 50, pp. 46402–46410. https://doi.org/10.1021/acsomega.2c05090
27. Sokolov D.Y., Yerezhep D., Vorobyova O., Ramos M.A., Shinbayeva A. Optical studies of thin flms of cryocondensed mixtures of water and admixture of nitrogen and argon. Materials (Basel), 2022, vol. 15, no. 21, pp. 441. https://doi.org/10.3390/ma15217441
Review
For citations:
Kenbay A.A., Golikov O.Yu., Aldiyarov A.U., Yerezhep D.E. Low-temperature cell for IR Fourier spectrometric investigation of hydrocarbon substances. Scientific and Technical Journal of Information Technologies, Mechanics and Optics. 2023;23(4):696-702. https://doi.org/10.17586/2226-1494-2023-23-4-696-702
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